Most orchids grow best with a slightly acidic pH around their root zone. However, you really need to research the type of orchid you are growing & determine what their prefered pH is. I understand Paphiopedilums actually prefer a slightly alkaline pH.
The fertilizer must be water soluble within a specific pH range so that the roots can take the nutrients up. There are macro and micronutrients which are important for the orchid's growth. I fertilize my orchids in distilled water which, like R.O., does not contain minerals or has had the majority of them removed. For that reason, there is nothing in the water to act as a buffering agent so the addition of fertilizer can cause the pH to drop to very acidic conditions which are harmful to the orchid. When pH is too acidic, toxic amounts of the fertilizer can be taken up by the roots. When the pH is too alkaline (base), the fertilizer is no longer water soluble and is not available to the roots for uptake.
Over the years, I have seen recommendations of anywhere from 5.8 to 7.0 (acid to neutral) pH for growing orchids. It is my understanding that a pH level of 6.4 to 6.5 will allow the best nutrient uptake of the majority of macro & micronutrients. However, all substrates (I believe LECA is an exception) decay & become more acidic over time and I grow my Phals in sphagnum moss which is an acidic substrate. For that reason, I aim for a pH of 6.5 to 6.9 which is low acidity towards neutral. I have also read that some diseases become more prominent at lower pH levels. This has worked well for me growing Phals & Cattleyas under T5 fluorescent lighting indoors.
In the end you will need to begin periodic testing of your fertilizer solution after it has run through the substrate you are growing your orchids in. To start though, you should make sure the fertilizer going in is in an optimal pH range for the best nutrient uptake possible. After awhile, you'll find what works best for you.
I do use liquid MSU Fertilizer for pure water plus I add Humid Acid & Protekt to the mix. If you decide to switch to MSU let me know & I will tell you how much I was advised to use in the spring/summer and fall/winter. I do fertilize 'weakly' at each watering & flush with tap water twice a month. In the early spring. I will also add Cal Mag separately just to make sure my orchids are getting enough calcium & magnesium when their growth begins. I will only do this three times because I don't want them to receive too much.
I did find an article on the Venice Orchid Society located at:
HOW YOUR WATER CAN AFFECT YOUR ORCHID – “PHood” – Venice Area Orchid Society. It stated that numerous white spots on your orchid leaves can also be caused by high alkalinity. Glad you ordered that pH meter. I think it will help you figure this out. Good luck!