Any time you have water, light and nutrition, you will have algae. Algae doesn't add to the culture, but its presence says that you're keeping the pots adequately watered and fed. By the same token, it's doesn't negatively affect it either - it's just an aesthetic issue.
Once it's there, you cannot remove it in place. Trying to do so via Physan will kill the stuff, leaving a mass of decomposing vegetation in the pot. The best thing to do - if you have to get rid of it - is to repot then put the old pot in the dishwasher.
If you really don't like the looks of it, a preventive treatment of Physan (1 tsp/gal) or bleach (1 oz/gal) about every 4- to 6 weeks will keep it at bay.
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