Donald's link is a good solution. I agree ants do not harm the orchids themselves; in fact, they can actually help open up old potting mixtures by burrowing. But the risk of them carrying diseases/pests is too great.
I had ants once in my Cattleya warneri, I flushed the pot with mildly soapy water (Dish soap-soap, lol) and they were gone pretty fast.
Good luck in getting rid of them.
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Matt-
Gone crazy, be back later.
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