If only talking about one plant, as Andrew said, it doesn't matter. The only variables I foresee here is flower age and longevity of reproductive parts. A flower can only recieve pollen for a certain window of time. Once the flower is past this prime, it will wilt and fall off faster than the pollen tubes grow towards the ovary. Fertilization never occurs and the flower just drops. Pollen, on the other hand, has a relatively long shelf life. Even if the flower's days are numbered, pollen remains viable.
Long story short: A selfing is a selfing, whatever flowers are used. But to increase your chances of setting seed, use a newer flower as the seed carrier. Pollen donor age doesn't matter as much as long as it's nice and clean and healthy looking. Try on a new and an old flower and see what works best.
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~Royal
"It does not require a majority to prevail, but rather an irate, tireless minority keen to set brush fires in people's minds." - Samuel Adams
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